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- W2049196001 abstract "The self-assembly of racemic and enantiopure binaphthyl-bis(amidopyridyl) ligands 1,1'-C(20)H(12){NHC(=O)-4-C(5)H(4)N}(2), 1, and 1,1'-C(20)H(12){NHC(=O)-3-C(5)H(4)N}(2), 2, with mercury(II) halides (HgX(2); X = Cl, Br, I) to form extended metal-containing arrays is described. It is shown that the self-assembly can lead to homochiral or heterochiral polymers or macrocycles, through self-recognition or self-discrimination of the ligand units, and the primary materials can further self-assemble through hydrogen bonding between amide substituents. In addition, the formation of macrocycles or polymers can be influenced by the presence or absence of excess mercury(II) halide, through a template effect, and mercury(II) halide inclusion complexes may be formed. In one case, an unusual polymeric compound was obtained, with 1 guest HgX(2) molecule for every 12 mercury halide units in the polymer." @default.
- W2049196001 created "2016-06-24" @default.
- W2049196001 creator A5021402070 @default.
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- W2049196001 date "2005-04-09" @default.
- W2049196001 modified "2023-10-13" @default.
- W2049196001 title "Self-Assembly of Chiral Coordination Polymers and Macrocycles: A Metal Template Effect on the Polymer−Macrocycle Equilibrium" @default.
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- W2049196001 doi "https://doi.org/10.1021/ic050097w" @default.
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