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• W2049203464 abstract "The imines 4 containing a diphenylcarbinol moiety serve as chiral ligands in novel enantiomerically pure imine-alkoxytitanium(IV) complexes. Depending on the molar ratio of the starting materials, imines 4 and titanium tetraisopropoxide, mono-chelated complexes 5 or bis-chelated complexes 6/7 result. The latter are formed diastereoselectively and the isomers 6 are main or exclusive products. Their (A) configuration is determined by a crystal-structure analysis of 6b. The bis-ligand complexes 6 or mixtures of 6/7, which are found to be remarkably stable, are used as precursors not only for the reactive dihalo complexes 8a/8b but also for the preparation of the mixed chloroisopropoxytitanium complex 8c." @default.
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• W2049203464 date "1998-06-01" @default.
• W2049203464 modified "2023-10-17" @default.
• W2049203464 title "Synthesis and Structure Determination of Novel Chiral Imine-Alkoxytitanium Complexes" @default.
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• W2049203464 doi "https://doi.org/10.1002/(sici)1099-0690(199806)1998:6<1063::aid-ejoc1063>3.0.co;2-w" @default.
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