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- W2049206925 abstract "Even though the fluid tilted smectic C (SmC) phase is one of the most common phases in thermotropic liquid crystals, the lyotropic analogue to SmC is practically unknown so far. One of the rare examples, a lyotropic liquid crystalline diol, which was reported in 1991 to show this phase, was re-examined by means of detailed X-ray diffraction and polarised optical microscopy. Although the diol possesses a smectic C promoting phenylpyrimidine core, it was not possible to verify the existence of a SmC-analogue lyotropic phase. Instead, the phase diagram shows the existence of five different lyotropic phases identified as nematic, lamellar Lα and hexagonal as well as two novel complex 2D-correlated lyophases. Results obtained by electron density calculations and X-ray diffraction data strongly suggest that the structure of one of these phases possesses a pseudo-c2mm symmetry and is built up of two different kinds of columns, whereas the other one is a ribbon phase of the oblique plane group p2." @default.
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- W2049206925 date "2012-01-01" @default.
- W2049206925 modified "2023-10-18" @default.
- W2049206925 title "The 2D-correlated structures of a lyotropic liquid crystalline diol with a phenylpyrimidine core" @default.
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- W2049206925 doi "https://doi.org/10.1039/c2jm32868b" @default.
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