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- W2049208675 abstract "Several benzimidazole derivatives having electron-withdrawing or -donating substituent(s) at the benzene moiety were used as models of the imidazole moiety of purine bases and their nitration with nitrogen dioxide and ozone (so-called Kyodai nitration) were examined. Products were extracted from the reaction mixture with AcOEt and their structures were analyzed. 1-Nitrobenzimidazole derivatives and unexpected 1-nitrobenzotriazole derivatives were identified. Although the yields of 1-nitrobenzimidazole derivatives were quite low, these were all new compounds that could be obtained only by Kyodai nitration. It was speculated that benzotriazoles were formed via 1-nitrobenzimidazoles and subsequent nitration toward benzotriazoles resulted in the formation of 1-nitrobenzotriazoles." @default.
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- W2049208675 date "2004-01-01" @default.
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- W2049208675 title "Product Analyses of Ozone Mediated Nitration of Benzimidazole Derivatives with Nitrogen Dioxide: Formation of 1-Nitrobenzimidazoles and Conversion to Benzotriazoles" @default.
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- W2049208675 doi "https://doi.org/10.1248/cpb.52.570" @default.
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