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- W2049222798 abstract "A new upper limit to the adiabatic ionization energy of trans-hydroxyoxomethyl, EI(t-HOCO)≤8.195±0.022 eV, is provided, producing a lower limit to the enthalpy of formation, ΔHf 0o(t-HOCO)≥−45.8±0.7 kcal/mol (≥−46.5±0.7 kcal/mol at 298 K). The spectrum shows progressions in CO and C–O stretches of HOCO+ and provides evidence for the excitation of OCO bend. In addition, the data tentatively suggest an ionization onset as low as 8.06±0.03 eV. While it is not clear whether the latter corresponds to cis or trans isomer, it may indicate that ΔHf 0o(HOCO) is even higher." @default.
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- W2049222798 date "2000-01-01" @default.
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- W2049222798 title "Photoionization of HOCO revisited: a new upper limit to the adiabatic ionization energy and lower limit to the enthalpy of formation" @default.
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- W2049222798 doi "https://doi.org/10.1016/s0009-2614(99)01267-1" @default.
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