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- W2049235524 abstract "The kinetics and mechanism of reaction of glassy carbon with a pure silicon melt or a Si + Mo melt were investigated. The results showed that the growth of a continuous reaction-formed SiC layer followed a fourth-power rate law in the temperature range of 1430° to 1510°C. A model that could explain the fourth-power rate law was developed. In this model, an internal electric field was assumed to be set up over the reaction-formed SiC layer through a negative space charge, and then the diffusion of the carbon-ion vacancies across this layer, driven predominately by this electric field, was considered as the rate-limiting step for the SiC growth. Neither an increase in the processing temperature nor an addition of 10 wt% Mo into the silicon melt had a significant influence on the reaction kinetics. X-ray diffraction analysis revealed that the reaction products were β-SiC, and β-SiC + MoSi2 for the Si-C and Si-C-Mo reactions, respectively." @default.
- W2049235524 created "2016-06-24" @default.
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- W2049235524 date "1995-09-01" @default.
- W2049235524 modified "2023-09-27" @default.
- W2049235524 title "Kinetics Model for the Growth of Silicon Carbide by the Reaction of Liquid Silicon with Carbon" @default.
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- W2049235524 doi "https://doi.org/10.1111/j.1151-2916.1995.tb08685.x" @default.
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