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- W2049274110 abstract "Abstract The reaction of the > P-Y− (Y = O; S) nucleophiles with the compounds possessing a C-Br bond and electron-withdrawing groups is described. The isolation of the products derived from dialkyl bromophosphates, the results of the 31P NMR studies, as well as the isolation of bromothiophosphate from the reaction mixture of > P-S− nucleophile and methyl α-bromocarboxylate, are further evidence for halophilic substitution as the principal process in the X-philic substitution/SET tandem mechanism operating in the reaction of these phosphorus nucleophiles with the bromederivatives possessing electron-withdrawing groups." @default.
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- W2049274110 date "1997-08-01" @default.
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- W2049274110 title "REACTIVITY OF THE ACIDS OF TRIVALENT PHOSPHORUS AND THEIR DERIVATIVES. PART IX. THE >P-0− AND >P-S− NUCLEOPHILES IN THE REACTIONS OF HALOPHILIC SUBSTITUTION" @default.
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- W2049274110 doi "https://doi.org/10.1080/10426509708040504" @default.
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