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• W2049284466 abstract "A plethora of binary and ternary intermetallic compounds has been assigned to the Gd14Ag51 structure type, crystallising in the hexagonal system (space group P6/m, a = 1264.30(18) pm, c = 933.58(11) pm for Gd14Ag51). Starting in the late 1960s, much work has been invested in the structural elucidation of these crystal structures. However, reliable single crystal data are scarce, and most structure type assignments have been performed merely on the basis of powder data. We have redetermined four representatives of the binary RE14Ag51 structure type (RE = Y, Ce, Gd, Tb) with modern high-precision single crystal X-ray methods. The assignment of the Gd14Ag51 structure type to space group P6/m was additionally verified by careful analysis of high resolution transmission electron micrographs. We emphasise the close relation of the Gd14Ag51 structure type to the structures of some recently described amalgams of similar composition focussing on disorder phenomena and structural complexity. Furthermore, we provide detailed information on synthesis as well as electrical and magnetic properties for Gd14Ag51, the parent compound of this structure family." @default.
• W2049284466 created "2016-06-24" @default.
• W2049284466 creator A5035872519 @default.
• W2049284466 creator A5089368178 @default.
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• W2049284466 date "2015-01-01" @default.
• W2049284466 modified "2023-09-28" @default.
• W2049284466 title "The <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si132.gif overflow=scroll><mml:mrow><mml:msub><mml:mrow><mml:mtext>Gd</mml:mtext></mml:mrow><mml:mrow><mml:mn>14</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mtext>Ag</mml:mtext></mml:mrow><mml:mrow><mml:mn>51</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math> structure type and its relation to some complex amalgam structures" @default.
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• W2049284466 doi "https://doi.org/10.1016/j.jallcom.2014.08.017" @default.
• W2049284466 hasPublicationYear "2015" @default.
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