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• W2049288544 endingPage "2363" @default.
• W2049288544 startingPage "2361" @default.
• W2049288544 abstract "Measurements of 7Li, 1H and 19F nuclear relaxation times and 7Li linewidths are reported for poly(propylene oxide) complexed with lithium salts (LiClO4, LiBF4 and LiAsF6). For PPO6LiBF4 and PPO8LiClO4 the onset of the 7Li motional line narrowing, occurs at approximately TG. The NMR decoupling methods was used to eliminate heteronuclear contribution to 7Li line shape. It was found that the Li- H interaction accounts for 80–90% of the linewidth. The remarkably similar temperature dependence of the measured 1H and 7Li spin-lattice relaxation rates, which shows rate maxima at 340–350 K in this PPOLi salts complexes, gives additional evidences for correlation between the cationic and the polymeric motions. The nuclear spin-lattice relaxation rates of the PPO complexes always peak at higher temperatures than the POE complexes, suggesting a lower ionic mobility for the former complexes. The frequency dependence of the relaxation rates cannot be described in the framework of the BPP theory." @default.
• W2049288544 created "2016-06-24" @default.
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• W2049288544 date "1995-10-01" @default.
• W2049288544 modified "2023-10-18" @default.
• W2049288544 title "Nuclear magnetic relaxation study of poly(propylene oxide)complexed with lithium salt" @default.
• W2049288544 cites W1963980036 @default.
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• W2049288544 doi "https://doi.org/10.1016/0013-4686(95)00194-j" @default.
• W2049288544 hasPublicationYear "1995" @default.
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