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- W2049290887 abstract "Abstract Partial reduction of a coordinated thiolester ligand led to the first example of an η 2 -bound aldehyde at a zerovalent tungsten carbonyl centre. Spectroscopic and crystallographic data support this assignment. Treatment of W(CO) 3 (RCN) 3 with N,N-tetramethylethylenediamine (tmeda) and an organic carbonyl compound led to a new family of η 2 -bound organic carbonyl complexes of the formula [W(CO) 3 (tmeda)( η 2 -RR′CO)]. Isolation and characterization of compounds containing formaldehyde, 4-methyl-benzaldehyde, pentafluorobenzaldehyde and hexafluoroacetone as π-ligands is reported." @default.
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- W2049290887 date "1996-08-01" @default.
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- W2049290887 title "π-Basicity of the (diamine)tricarbonyltungsten(0) fragment stabilizing η2-aldehyde complexes at tungsten(0)" @default.
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- W2049290887 doi "https://doi.org/10.1016/0277-5387(96)00038-1" @default.
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