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- W2049309209 abstract "Recent suggestions by Levine for exactly treating hydrogenic impurities on idealized semiconductor surfaces are extended to the case of another exactly soluble model, a hydrogenic impurity on the boundary of a semi-infinite, dense electron gas. The surface selection rule $l+m=mathrm{odd}$ is found to apply to this hypothetical surface. This rule is equivalent to the requirement that impurity wave functions have a nodal plane on the boundary. Unlike the dielectric case, the allowed wave functions of the present hypothetical model extend into the vacuum half-space but not into the electron-gas half-space. A surface dipole is thus formed which is directed into the surface, thus increasing the surface barrier for electron emission.The exact high-density results are extrapolated to densities that exist within conduction bands of real metals. With this extrapolation it is found that the exact high-density theory is useful in understanding the role of ion-core screening when small atoms, such as hydrogen or lithium, are adsorbed on real metal surfaces. The present results permit interpretation of previously unexplained data for lithium adsorption on metals." @default.
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- W2049309209 title "Nodal Hydrogenic Wave Functions of Impurities on Bounded-Electron-Gas Surfaces" @default.
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- W2049309209 doi "https://doi.org/10.1103/physrev.154.662" @default.
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