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- W2049367049 abstract "Orientation and charge transfer upon adsorption of ethanethiol on Cu(1 1 1) surface at 85 K has been investigated by S K-edge near edge X-ray absorption fine structure (NEXAFS) and X-ray photoelectron spectroscopy (XPS) techniques. Exposure-dependent S K-edge NEXAFS identified the monolayer saturation at ∼0.8 L exposure. Polarization-dependent NEXAFS spectra of submonolayer ethanethiol shows that S–C bond is tilted 37±7° from the surface. Temperature-dependent NEXAFS spectra shows that ethyl thiolate starts breaking at 300–350 K and atomic sulfur creates. A significant amount of charge transfer (1.4 electrons) from copper to ethanethiol molecules has measured by S 1s XPS technique." @default.
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- W2049367049 date "2003-01-01" @default.
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- W2049367049 title "Orientation and charge transfer upon adsorption of ethanethiol on Cu() surface at 85 K" @default.
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