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- W2049382092 abstract "The magnetic circular dichroism of the K-band in the alkali halides RbCl, RbBr, RbI, KCl, KBr, and KI has been measured at temperatures between 4.2 and 77 °K. The magnetic field up to 50 kG was produced by a superconducting solenoid. We interpret the experimental results using the method of moments. The spin-orbit splitting and the orbital g-factors of the excited states due to the K-band are determined. Furthermore we obtain matrix elements describing the mixture of the excited states giving rise to F-and K-bands. In accordance with calculations of Smith [15] the measurements confirm the Mott-Gurney model, which attributes the K-band mainly to 1s-3p transitions. Der magnetische zirkulare Dichroismus der K-Bande wurde in den Alkalihalogeniden RbCl, RbBr, RbJ, KCl, KBr und KJ bei Temperaturen von 4.2 bis 77 °K gemessen. Als Magnet diente eine Supraleitungsspule, mit der Magnetfelder bis zu 50 kG erzeugt werden können. Die Auswertung der Messungen geschieht nach der Methode der Momente. Man erhält Spin-Bahn-Aufspaltungen und orbitale g-Faktoren der angeregten Zustände des K-Überganges. Außerdem werden Matrixelemente bestimmt, die die Mischung der angeregten Zustände des K- und F-Überganges beschreiben. In Übereinstimmung mit Rechnungen von Smith [15] bestätigen die Messungen das Mott-Gurney-Modell, das die K-Bande im wesentlichen 1s-3p-Übergängen zuordnet." @default.
- W2049382092 created "2016-06-24" @default.
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- W2049382092 date "1969-01-01" @default.
- W2049382092 modified "2023-09-27" @default.
- W2049382092 title "Magnetic Circular Dichroism of the K-Band in Alkali Halides" @default.
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- W2049382092 doi "https://doi.org/10.1002/pssb.19690360128" @default.
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