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• W2049405318 startingPage "2176" @default.
• W2049405318 abstract "Two new classes of proline-based P,O and P,N ligands were prepared and applied in the iridium-catalyzed asymmetric hydrogenation of alkenes. Both types of ligands induced high enantioselectivities in the hydrogenation of trisubstituted CC bonds. Iridium complexes derived from P,O ligands bearing sterically demanding amide or urea groups at the pyrrolidine N-atom proved to be especially efficient catalysts for the conjugate reduction of α,β-unsaturated esters and ketones, whereas analogous P,N ligands led to better results with dialkyl-phenyl-substituted alkenes and an allylic alcohol as substrates." @default.
• W2049405318 created "2016-06-24" @default.
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• W2049405318 date "2012-11-01" @default.
• W2049405318 modified "2023-10-18" @default.
• W2049405318 title "Chiral Proline-Based P,O and P,N Ligands for Iridium-Catalyzed Asymmetric Hydrogenation" @default.
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• W2049405318 doi "https://doi.org/10.1002/hlca.201200437" @default.
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