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- W2049415022 abstract "Reaction of NaMn(CO)5 with trans-1-bromopenta-2,4-diene in tetrahydrofuran at −78°C gives (η1-2,4-pentadienyl)Mn(CO)5 (1) in excellent yield. Compound 1 undergoes η1 → syn-η3 → η5 transformation and, yields (syn-η3-2,4-pentadienyl)Mn)(CO)4 (2) and (η5-pentadienyl)Mn(CO)3 (3), respectively. The reactions of 1 with the electrophiles tetracyanoethylene (TCNE) and sulfur dioxide (SO2) were investigated. Compound 1 undergoes a [4 + 2] cycloaddition with TCNE and an insertion reaction with SO2. The product are characterized by elemental analysis and spectroscopic data." @default.
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- W2049415022 date "1987-02-01" @default.
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- W2049415022 title "Synthesis, characterization and reactivity of pentacarbonyl(η1-2,4-pentadienyl)manganese" @default.
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- W2049415022 doi "https://doi.org/10.1016/s0022-328x(00)98977-0" @default.
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