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• W2049452413 abstract "We present a general algorithm for predicting the linear rheology of branched polymers. While the method draws heavily on existing theoretical understanding of the relaxation processes in entangled polymer melts, a number of new concepts are developed to handle diverse polymer architectures including branch-on-branch structures. We validate the algorithm with experimental examples from model polymer architectures to fix the parameters of the model. We use experimentally determined parameters to generate a numerical ensemble of branched metallocene-catalyzed polyethylene resins. Application of our algorithm shows the importance of branch-on-branch chains in the system and predicts the linear rheology with good quantitative agreement over a wide range of branching density and molecular weight." @default.
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• W2049452413 date "2006-03-01" @default.
• W2049452413 modified "2023-10-17" @default.
• W2049452413 title "Computational linear rheology of general branch-on-branch polymers" @default.
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• W2049452413 doi "https://doi.org/10.1122/1.2167487" @default.
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