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- W2049492048 abstract "Molar heat capacities of n-butanol and the azeotropic mixture in the binary system [water (x=0.716) plus n-butanol (x=0.284)] were measured with an adiabatic calorimeter in a temperature range from 78 to 320 K. The functions of the heat capacity with respect to thermodynamic temperature were established for the azeotropic mixture. A glass transition was observed at (111.9±1.2) K. The phase transitions took place at (179.26±0.77) and (269.69±0.14) K corresponding to the solid-liquid phase transitions of n-butanol and water, respectively. The phase-transition enthalpy and entropy of water were calculated. A thermodynamic function of excess molar heat capacity with respect to temperature was established, which took account of physical mixing, destructions of self-association and cross-association for n-butanol and water, respectively. The thermodynamic functions and the excess thermodynamic ones of the binary systems relative to 298.15 K were derived based on the relationships of the thermodynamic functions and the function of the measured heat capacity and the calculated excess heat capacity with respect to temperature." @default.
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- W2049492048 date "2005-10-01" @default.
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- W2049492048 title "Measurements of the Heat Capacity of an Azeotropic Mixture of Water andn-Butanol from 78 to 320 K" @default.
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- W2049492048 doi "https://doi.org/10.1002/cjoc.200591297" @default.
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