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- W2049496798 abstract "Double quantum coherence (DQC) ESR spectroscopy is applied to measure the Cu2+–Cu2+ distance in the EcoRI-DNA complex. A simple method is proposed to reduce the contribution of nuclear hyperfine and quadrupole interactions to such data. The effects of such interactions between the electron spin of Cu2+ and neighboring nuclei on the DQC data make it difficult to measure the nanometer range interspin distance. The DQC data is in good agreement with results obtained by double electron electron resonance (DEER) spectroscopy. At the same time, the signal-to-noise ratio per shot in DQC is high. Taken together, these results provide impetus for further development of paramagnetic metal ion-based DQC techniques." @default.
- W2049496798 created "2016-06-24" @default.
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- W2049496798 date "2013-05-10" @default.
- W2049496798 modified "2023-10-18" @default.
- W2049496798 title "Sensitive Cu<sup>2+</sup>–Cu<sup>2+</sup> Distance Measurements in a Protein–DNA Complex by Double-Quantum Coherence ESR" @default.
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- W2049496798 doi "https://doi.org/10.1021/jp4037149" @default.
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