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- W2049521392 abstract "(a) Theoretical derivation of the Rao's relation R V = a ( T c / M ) 1/6 v c has been performed on the basis of the Lennard-Jones and Devonshire's liquid model and using Wentorf, Buehler, Hirschfelder and Curtiss' equation of state. Here R V means the molecular sound velocity defined by R V =( M /ρ) V 1/3 , with M the molecular weight, ρ the density and V the sound velocity; T c and v c mean the critical temperature and the critical volume respectively, and a is an empirical constant with average value 2.68, according to Rao. The theoretical value of a obtained in this paper is 4.64. (b) Re-examination of Rao's relation has been performed on organic liquids and on some liquified gases employing existing ultrasonic velocity data and the following average values have been obtained: a exp =2.86 (on five liquified gases), a exp =2.69 (on 21 organic liquids except alcohols, acids and acetonitrile). The a exp for alcohols and acids are somewhat lower, the lowest example being a exp =1.825 for acetic acid. These..." @default.
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- W2049521392 date "1954-01-01" @default.
- W2049521392 modified "2023-09-28" @default.
- W2049521392 title "On Molecular Sound Velocity of Liquids. III Consideration on the Rao's Relation on the Dependence of Molecular Sound Velocity on Critical Constants" @default.
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- W2049521392 doi "https://doi.org/10.1143/jpsj.9.73" @default.
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