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- W2049533090 abstract "Soil heating, as for example experienced during vegetation fires, often increases soil water repellency; however, no detailed analysis of the soil chemical changes associated with this increase has been conducted to date. Here we characterize the changes in organic compound composition associated with heat-induced increases in water repellency for three Australian eucalypt-forest soils (one sandy loam, two sands). Laboratory heating (300°C) strongly increased water drop penetration times (WDPTs) in all soils. Soils were extracted by accelerated solvent extraction (ASE) with an iso-propanol/ammonia mixture (IPA/NH3 95:5) and pure iso-propanol (IPA). Extracts were fractionated into less and more polar fractions and analysed by GC-MS. Water repellency was eliminated in unheated and heated soils by IPA/NH3, but not by pure IPA. Before heating, total solvent extracts were dominated by n-alkanols, terpenoids, C16 acid, C29 alkane, β-sitosterol and polar compounds. After heating, dominant compounds were aromatic acids, aldehydes, levoglucosan, simple sugars and glycosides. Heating resulted in a sharp absolute decrease of homologous aliphatic series of alkanols and alkanes, a shift of fatty acid signature to members <C20 and an increase in total content of aromatic compounds. Heating also caused the formation of complex high-molecular-weight compounds detected in the more polar fractionated extracts and low-molecular-weight oxo- and hydroxyacids and aromatics in the IPA/NH3 solvent. We speculate that these compounds in conjunction with fatty acids of <C12 interact with organic and mineral soil surfaces and cause the observed strong increases in soil water repellency following heating." @default.
- W2049533090 created "2016-06-24" @default.
- W2049533090 creator A5031117461 @default.
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- W2049533090 date "2011-02-17" @default.
- W2049533090 modified "2023-10-11" @default.
- W2049533090 title "Changes in soil organic compound composition associated with heat-induced increases in soil water repellency" @default.
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- W2049533090 doi "https://doi.org/10.1111/j.1365-2389.2011.01350.x" @default.
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