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- W2049534476 abstract "Oxidation of 1,2,2-tris(4-dimethylaminophenyl)- and 2,2-bis(4-dimethylaminophenyl)-1-phenylacenaphthen-1-ols 1a,b with I2 induced the C1C2 bond fission to give 8-aroylnaphthalen-1-yl-bis(4-dimethylaminophenyl)carbenium derivatives 2a,b+, the intramolecular Lewis acid–base pairs. Treatment of 1 with HBF4 did not induce the expected COH bond heterolysis but caused fission of COH and C1C2 bonds to give exactly the same carbenium 2+." @default.
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- W2049534476 date "2003-08-01" @default.
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- W2049534476 title "Formation of keto-carbeniums from 1,2,2-triarylacenaphthen-1-ols by breaking a long CC bond: unusual alcohol protonolysis accompanied by formal hydride abstraction" @default.
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- W2049534476 doi "https://doi.org/10.1016/s0040-4039(03)01459-x" @default.
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