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- W2049554920 abstract "Abstract Pure Na 2 Ti 6 O 13 phase was successfully prepared from partially washed (Na,H) Ti O nanotubes and used as an insertion material for lithium ions. Results show that the structure can accommodate upto 3 mol of lithium per 1 mol of Na 2 Ti 6 O 13 . Accommodation of 0.5 mol of lithium per one titanium atom corresponds to the partial reduction of Ti 4+ to Ti 3+ and occurs several 100s of millivolts lower than typically encountered for titanium in an octahedral oxygen environment such as Li 4 Ti 5 O 12 . Lithium insertion into this phase was evaluated using especially in situ X-ray. Lithium insertion into Na 2 Ti 6 O 13 phase includes three domains corresponding to two solid–solutions and a biphasic transition in the potential range between 1.5 V and 1.0 V vs. lithium. The process is very reversible so that after re-oxidation the structure is completely preserved. Capacity fading observed during the cycling is explained by parasitic reactions attributed to a catalytic effect of the exposed bare surface on the electrolyte degradation." @default.
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- W2049554920 date "2006-04-01" @default.
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- W2049554920 title "Reversible lithium insertion into Na2Ti6O13 structure" @default.
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- W2049554920 doi "https://doi.org/10.1016/j.elecom.2006.02.017" @default.
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