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- W2049595890 abstract "Values of the second virial coefficientBof benzene and cyclohexane have been obtained from measurements of the excess molar enthalpyHmEof {yN2+ (1 −y)C6H12} and {yN2+ (1 −y)C6H12} measured at standard atmospheric pressure over the temperature range 333.2 to 433.2 K. In a hypothetical mixture of an ideal gas with benzene or cyclohexane a measurement ofHmEis equivalent to a measurement of the isothermal Joule –Thomson coefficient φ22 of the hydrocarbon. In a mixture of the nearly ideal gas nitrogen with hydrocarbon, φ11for nitrogen is small. The cross term isothermal Joule –Thomson coefficient φ12is also small and can be calculated with adequate accuracy using an established combining rule. Potential parameters which fitB22and φ22for the hydrocarbon can then be calculated from theHmEmeasurements. It is shown that theHmEmeasurements yield values of φ22for benzene and cyclohexane which are in good agreement with values obtained from throttling experiments, and that values ofB22agree well with those obtained from ( ρ, ρn,T). It is suggested thatHmEmeasurements on these mixtures might be useful for testing the performance of mixing calorimeters, and empirical equations which if the measurments at mole fractiony= 0.5 are given." @default.
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- W2049595890 date "1996-01-01" @default.
- W2049595890 modified "2023-09-24" @default.
- W2049595890 title "Second virial coefficients of benzene and cyclohexane from measurements of the excess molar enthalpy of (0.5N2+ 0.5C6H6) and (0.5N2+ 0.5C6H12) from 333.2 K to 433.2 K" @default.
- W2049595890 doi "https://doi.org/10.1006/jcht.1996.0004" @default.
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