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- W2049602009 abstract "Abstract The dependence of the intrinsic viscosity [η] on molecular weight and side-chain length for brush-shaped polymers is analyzed using a simplified expression for [η], in which a brush-shaped polymer is modeled as a linear chain with a contour length equal to that of the backbone of the brush-shaped chain and a repeat unit molar mass that includes the molar mass of the side chain. The treatment is used to estimate the ratio â/âref of the persistence length â of the brush-shaped chain relative to a reference chain as a function of side-chain molecular weight. Values of â/âref deduced for data on a series of brush-shaped polymers are found to be in good accord with values derived in a more complete treatment of the dependence of [η] on M based on the wormlike chain model. Estimates of â/âref are also given for a series of poly(alkyl methacrylate) chains as a function of the alkyl chain length, and the approximate expression is applied to the evaluation of the true molecular weight from the apparent mo..." @default.
- W2049602009 created "2016-06-24" @default.
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- W2049602009 date "2007-06-28" @default.
- W2049602009 modified "2023-10-18" @default.
- W2049602009 title "An Approximation for the Intrinsic Viscosity of Brush-Shaped Polymers" @default.
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- W2049602009 doi "https://doi.org/10.1080/10236660701355329" @default.
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