Matches in SemOpenAlex for { <https://semopenalex.org/work/W2049641141> ?p ?o ?g. }
- W2049641141 endingPage "427" @default.
- W2049641141 startingPage "419" @default.
- W2049641141 abstract "Abstract In this work, we have used electron paramagnetic resonance (EPR) spectroscopy of the small spin label di‐ tert ‐butyl nitroxide (DTBN), which partitions the aqueous and hydrocarbon phases, to study the interaction of the terpenes α‐terpineol, 1,8‐cineole, l (−)‐carvone and (+)‐limonene with the uppermost skin layer, the stratum corneum, and the membrane models of 1,2‐dipalmitoyl‐ sn ‐glycero‐3‐phosphatidylcholine (DPPC) and 1,2‐dimyristoyl‐ sn ‐glycero‐3‐phosphocholine (DMPC). The EPR spectra indicated that the terpenes increase both the partition coefficient and the rotational correlation time of the spin labels in the stratum corneum membranes, whereas similar effects were observed in the DMPC and DPPC bilayers only at temperatures below the liquid‐crystalline phase. The EPR parameter associated to probe polarity inside the membranes showed thermotropically induced changes, suggesting relocations of spin probe, which were dependent on the membrane phases. While the DMPC and DPPC bilayers showed abrupt changes in the partitioning and rotational correlation time parameters in the phase transitions, the SC membranes were characterized by slight changes in the total range of measured temperatures, presenting the greatest changes or membranes reorganizations in the temperature range of ~50 to ~74 °C. The results suggest that terpenes act as spacers, weakening the hydrogen‐bonded network at the polar interface and thus fluidizing the stratum corneum lipids." @default.
- W2049641141 created "2016-06-24" @default.
- W2049641141 creator A5002625175 @default.
- W2049641141 creator A5026735582 @default.
- W2049641141 creator A5027035363 @default.
- W2049641141 creator A5068031802 @default.
- W2049641141 date "2010-04-02" @default.
- W2049641141 modified "2023-09-30" @default.
- W2049641141 title "Molecular Dynamics and Partitioning of Di-tert-butyl Nitroxide in Stratum Corneum Membranes: Effect of Terpenes" @default.
- W2049641141 cites W1975775428 @default.
- W2049641141 cites W1978124142 @default.
- W2049641141 cites W1980754760 @default.
- W2049641141 cites W1981770102 @default.
- W2049641141 cites W1982205525 @default.
- W2049641141 cites W1983122413 @default.
- W2049641141 cites W1985857554 @default.
- W2049641141 cites W1987071172 @default.
- W2049641141 cites W1987851345 @default.
- W2049641141 cites W1995974987 @default.
- W2049641141 cites W1997049443 @default.
- W2049641141 cites W1999650887 @default.
- W2049641141 cites W2017942951 @default.
- W2049641141 cites W2026873054 @default.
- W2049641141 cites W2027431875 @default.
- W2049641141 cites W2029542139 @default.
- W2049641141 cites W2029554393 @default.
- W2049641141 cites W2041101919 @default.
- W2049641141 cites W2042757604 @default.
- W2049641141 cites W2046029852 @default.
- W2049641141 cites W2054132894 @default.
- W2049641141 cites W2068016481 @default.
- W2049641141 cites W2074846432 @default.
- W2049641141 cites W2082910860 @default.
- W2049641141 cites W2085114701 @default.
- W2049641141 cites W2087336050 @default.
- W2049641141 cites W2088407816 @default.
- W2049641141 cites W2091044472 @default.
- W2049641141 cites W2128444449 @default.
- W2049641141 cites W2164014242 @default.
- W2049641141 cites W2481785506 @default.
- W2049641141 cites W40251318 @default.
- W2049641141 doi "https://doi.org/10.1007/s11745-010-3407-2" @default.
- W2049641141 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20361269" @default.
- W2049641141 hasPublicationYear "2010" @default.
- W2049641141 type Work @default.
- W2049641141 sameAs 2049641141 @default.
- W2049641141 citedByCount "15" @default.
- W2049641141 countsByYear W20496411412012 @default.
- W2049641141 countsByYear W20496411412013 @default.
- W2049641141 countsByYear W20496411412014 @default.
- W2049641141 countsByYear W20496411412015 @default.
- W2049641141 countsByYear W20496411412016 @default.
- W2049641141 countsByYear W20496411412017 @default.
- W2049641141 countsByYear W20496411412018 @default.
- W2049641141 countsByYear W20496411412020 @default.
- W2049641141 countsByYear W20496411412022 @default.
- W2049641141 countsByYear W20496411412023 @default.
- W2049641141 crossrefType "journal-article" @default.
- W2049641141 hasAuthorship W2049641141A5002625175 @default.
- W2049641141 hasAuthorship W2049641141A5026735582 @default.
- W2049641141 hasAuthorship W2049641141A5027035363 @default.
- W2049641141 hasAuthorship W2049641141A5068031802 @default.
- W2049641141 hasConcept C111998727 @default.
- W2049641141 hasConcept C113196181 @default.
- W2049641141 hasConcept C121332964 @default.
- W2049641141 hasConcept C142724271 @default.
- W2049641141 hasConcept C15920480 @default.
- W2049641141 hasConcept C169912494 @default.
- W2049641141 hasConcept C178790620 @default.
- W2049641141 hasConcept C185592680 @default.
- W2049641141 hasConcept C187961010 @default.
- W2049641141 hasConcept C192552737 @default.
- W2049641141 hasConcept C2778370115 @default.
- W2049641141 hasConcept C2779394729 @default.
- W2049641141 hasConcept C39944091 @default.
- W2049641141 hasConcept C41625074 @default.
- W2049641141 hasConcept C43617362 @default.
- W2049641141 hasConcept C44280652 @default.
- W2049641141 hasConcept C46141821 @default.
- W2049641141 hasConcept C521977710 @default.
- W2049641141 hasConcept C55493867 @default.
- W2049641141 hasConcept C71924100 @default.
- W2049641141 hasConcept C79123411 @default.
- W2049641141 hasConceptScore W2049641141C111998727 @default.
- W2049641141 hasConceptScore W2049641141C113196181 @default.
- W2049641141 hasConceptScore W2049641141C121332964 @default.
- W2049641141 hasConceptScore W2049641141C142724271 @default.
- W2049641141 hasConceptScore W2049641141C15920480 @default.
- W2049641141 hasConceptScore W2049641141C169912494 @default.
- W2049641141 hasConceptScore W2049641141C178790620 @default.
- W2049641141 hasConceptScore W2049641141C185592680 @default.
- W2049641141 hasConceptScore W2049641141C187961010 @default.
- W2049641141 hasConceptScore W2049641141C192552737 @default.
- W2049641141 hasConceptScore W2049641141C2778370115 @default.
- W2049641141 hasConceptScore W2049641141C2779394729 @default.
- W2049641141 hasConceptScore W2049641141C39944091 @default.
- W2049641141 hasConceptScore W2049641141C41625074 @default.
- W2049641141 hasConceptScore W2049641141C43617362 @default.