Matches in SemOpenAlex for { <https://semopenalex.org/work/W2049658879> ?p ?o ?g. }
- W2049658879 endingPage "6019" @default.
- W2049658879 startingPage "6011" @default.
- W2049658879 abstract "A four-step route was designed to synthesize 3,8-benzo[c]cinnoline dicarboxylic acid (4). New conjugated polymers, POXD (I) and POXD (T), containing benzo[c]cinnoline and oxadiazole moieties, were obtained by thermal cyclodehydration of their soluble polyhydrazide precursors PHA (I) and PHA (T), respectively. Two reduction peaks were observed for these new conjugated polymers during CV cathodic scan. From the CV voltammograms combined with the results from molecular simulation, we concluded that the first reduction occurred at oxadiazole moiety and benzo[c]cinnoline moiety was responsible for the second reduction. It indicates that oxadiazole has stronger electron affinity than benzo[c]cinnoline. We proposed a mechanism to explain this two-stage reduction process. Due to the planar and electron-accepting ability of benzo[c]cinnoline and oxadiazole moieties, POXD (I) and POXD (T) exhibited very low LUMO (−3.42 and −3.45 eV) and HOMO (−6.23 and −6.27 eV) energy levels. They can be used as hole-blocking or electron-injection layers for OLED applications." @default.
- W2049658879 created "2016-06-24" @default.
- W2049658879 creator A5002372240 @default.
- W2049658879 creator A5006059982 @default.
- W2049658879 creator A5025751238 @default.
- W2049658879 creator A5038116531 @default.
- W2049658879 creator A5050855167 @default.
- W2049658879 creator A5069840752 @default.
- W2049658879 creator A5087320238 @default.
- W2049658879 date "2011-12-01" @default.
- W2049658879 modified "2023-09-27" @default.
- W2049658879 title "Investigations on the electrochemical properties of new conjugated polymers containing benzo[c]cinnoline and oxadiazole moieties" @default.
- W2049658879 cites W1968087011 @default.
- W2049658879 cites W1974219338 @default.
- W2049658879 cites W1984477028 @default.
- W2049658879 cites W1984880144 @default.
- W2049658879 cites W1986719405 @default.
- W2049658879 cites W1988266339 @default.
- W2049658879 cites W1990956323 @default.
- W2049658879 cites W1992139458 @default.
- W2049658879 cites W1993940760 @default.
- W2049658879 cites W1997574379 @default.
- W2049658879 cites W2001154320 @default.
- W2049658879 cites W2007307325 @default.
- W2049658879 cites W2011886623 @default.
- W2049658879 cites W2012604167 @default.
- W2049658879 cites W2018231107 @default.
- W2049658879 cites W2022321554 @default.
- W2049658879 cites W2032695513 @default.
- W2049658879 cites W2039699123 @default.
- W2049658879 cites W2048400654 @default.
- W2049658879 cites W2054048682 @default.
- W2049658879 cites W2054203260 @default.
- W2049658879 cites W2055331484 @default.
- W2049658879 cites W2055470169 @default.
- W2049658879 cites W2056544067 @default.
- W2049658879 cites W2064551653 @default.
- W2049658879 cites W2070597851 @default.
- W2049658879 cites W2071134066 @default.
- W2049658879 cites W2073982067 @default.
- W2049658879 cites W2074538600 @default.
- W2049658879 cites W2075109970 @default.
- W2049658879 cites W2079433525 @default.
- W2049658879 cites W2079658025 @default.
- W2049658879 cites W2082531853 @default.
- W2049658879 cites W2084263898 @default.
- W2049658879 cites W2085117145 @default.
- W2049658879 cites W2085436009 @default.
- W2049658879 cites W2086429248 @default.
- W2049658879 cites W2111393217 @default.
- W2049658879 cites W2112517561 @default.
- W2049658879 cites W2127933435 @default.
- W2049658879 cites W2128527691 @default.
- W2049658879 cites W2129529288 @default.
- W2049658879 cites W2132707359 @default.
- W2049658879 cites W2951042007 @default.
- W2049658879 cites W3167327808 @default.
- W2049658879 cites W4211110766 @default.
- W2049658879 doi "https://doi.org/10.1016/j.polymer.2011.10.059" @default.
- W2049658879 hasPublicationYear "2011" @default.
- W2049658879 type Work @default.
- W2049658879 sameAs 2049658879 @default.
- W2049658879 citedByCount "22" @default.
- W2049658879 countsByYear W20496588792012 @default.
- W2049658879 countsByYear W20496588792014 @default.
- W2049658879 countsByYear W20496588792015 @default.
- W2049658879 countsByYear W20496588792016 @default.
- W2049658879 countsByYear W20496588792017 @default.
- W2049658879 countsByYear W20496588792018 @default.
- W2049658879 countsByYear W20496588792019 @default.
- W2049658879 countsByYear W20496588792021 @default.
- W2049658879 countsByYear W20496588792022 @default.
- W2049658879 crossrefType "journal-article" @default.
- W2049658879 hasAuthorship W2049658879A5002372240 @default.
- W2049658879 hasAuthorship W2049658879A5006059982 @default.
- W2049658879 hasAuthorship W2049658879A5025751238 @default.
- W2049658879 hasAuthorship W2049658879A5038116531 @default.
- W2049658879 hasAuthorship W2049658879A5050855167 @default.
- W2049658879 hasAuthorship W2049658879A5069840752 @default.
- W2049658879 hasAuthorship W2049658879A5087320238 @default.
- W2049658879 hasConcept C112613896 @default.
- W2049658879 hasConcept C14158195 @default.
- W2049658879 hasConcept C155647269 @default.
- W2049658879 hasConcept C178790620 @default.
- W2049658879 hasConcept C185592680 @default.
- W2049658879 hasConcept C188027245 @default.
- W2049658879 hasConcept C2776061638 @default.
- W2049658879 hasConcept C2776568683 @default.
- W2049658879 hasConcept C2779448499 @default.
- W2049658879 hasConcept C32909587 @default.
- W2049658879 hasConcept C521977710 @default.
- W2049658879 hasConcept C71240020 @default.
- W2049658879 hasConceptScore W2049658879C112613896 @default.
- W2049658879 hasConceptScore W2049658879C14158195 @default.
- W2049658879 hasConceptScore W2049658879C155647269 @default.
- W2049658879 hasConceptScore W2049658879C178790620 @default.
- W2049658879 hasConceptScore W2049658879C185592680 @default.
- W2049658879 hasConceptScore W2049658879C188027245 @default.