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- W2049668730 abstract "By varying the Fe/Cr ratio in FeCr 2 S 4 we have found that a slight excess of Fe has a substantial effect on the Mössbauer spectra, while a small deficit has virtually no effect. The paramagnetic spectra of Fe 1.06 Cr 1.94 S 4 show the superposition of a singlet and a doublet, the latter being attributed to Fe 4+ on A sites having one nearest neighbor B-site Cr 3+ replaced by an Fe 2+ . A lambda-type peak in the heat capacity of Fe 0.97 Cr 2 S 4 is observed at 9.25 K, indicative of the cooperative antiferrodistortive Jahn-Teller transition observed earlier with Mössbauer spectroscopy." @default.
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- W2049668730 date "1976-03-01" @default.
- W2049668730 modified "2023-09-26" @default.
- W2049668730 title "Effect of small variations of the Fe/Cr ratio on the 57 Fe Mössbauer spectra of FeCr2S4" @default.
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