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• W2049682718 endingPage "575" @default.
• W2049682718 startingPage "574" @default.
• W2049682718 abstract "1-Halovinyllithium carbenoids can undergo the Fritsch–Buttenberg–Wiechell (FBW) rearrangement to form alkynes. This reaction is quite facile when a hydrogen atom is present on carbon 2. The gas-phase reaction mechanism may consist of a single-step or several steps, depending on the aggregation state of the carbenoid. We examined the FBW reaction of 1-fluoro, chloro-, and bromovinyllithium in the monomer and two isomeric dimers. The migratory aptitude of the hydrogen atoms is dependent on the halogen and the aggregation state." @default.
• W2049682718 created "2016-06-24" @default.
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• W2049682718 date "2009-06-05" @default.
• W2049682718 modified "2023-09-27" @default.
• W2049682718 title "Fritsch–Buttenberg–Wiechell (FBW) Reaction of 1-Halovinyllithium Carbenoids: A Computational Study" @default.
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• W2049682718 doi "https://doi.org/10.1246/cl.2009.574" @default.
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