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- W2049708145 abstract "Abstract Pyrolysis of aryl substituted phenacylbenzyldimethylammonium compounds was studied in a gas chromatographic injector. The thermal decomposition products were identified by gas chromatography/mass spectrometry. The influence of bromide and boron tetrafluoride anions on the pyrolysis was studied. The major process concerning the bromide ion was dealkylation via loss of the benzyl group; the minor process was dealkylation via loss of the phenacyl group. In both cases corresponding tertiary amines were formed. When the non-nucleophilic boron tetrafluoride was used as anion, no dealkylation occurred; the benzyl group rearranged and a tertiary amine was formed. The gas flow-rate (8–38 ml min −1 ) and the injector temperature (250–400°C) had minimal influence on the rearrangement." @default.
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- W2049708145 date "1993-12-01" @default.
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- W2049708145 title "Dealkylation and rearrangement of phenacylammonium salts in a gas chromatographic injector" @default.
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- W2049708145 doi "https://doi.org/10.1016/0165-2370(93)80009-o" @default.
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