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- W2049711679 abstract "Interaction of deprotonated acetylcyclopropane cyclohexylimine with several aliphatic alkyl halides, epoxides, and aldehydes efficiently gave the corresponding cyclopropyl ketones. Some of the respective alcohols were rearranged in a highly stereoselective manner under the action of trimethylsilyl bromide in the presence of zinc bromide into the corresponding linear (E)-homoallyl bromides. The latter were used, in turn, as key intermediates in concise syntheses of thirteen terminally functionalized straight-chain oligoolefins which are known to constitute acetogenin pheromonal components for more than 65 species of lepidopteran insects." @default.
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- W2049711679 date "1991-01-01" @default.
- W2049711679 modified "2023-10-09" @default.
- W2049711679 title "Acetylcyclopropane as a five–carbon building block in the synthesis of some acetogenin insect pheromones" @default.
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- W2049711679 doi "https://doi.org/10.1039/p19910002639" @default.
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