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• W2049717259 endingPage "2456" @default.
• W2049717259 startingPage "2456" @default.
• W2049717259 abstract "The preparation and properties of two new series of rare-earth organic frameworks, [Ln2(cam)2(NO3)2(MeOH)4]n (Ln = Gd (1·Gd), Tb (1·Tb), Dy (1·Dy), Ho (1·Ho) and Er (1·Er)) and [Ln(D-cam)(O2CH)]n (Ln = Tb (2·Tb), Dy (2·Dy), Ho (2·Ho) and Er (2·Er); D-H2cam = (+) D-camphoric acid) under solvothermal conditions is described. Single-crystal X-ray diffraction analyses revealed that the 1·Gd–1·Er compounds are isostructural and crystallize in the monoclinic space group P21/n with the chiral D-camphorate ligand racemized, while the 2·Tb–2·Er compounds are isostructural and crystallize as orthorhombic with the chiral space group P21212121. The structures of the 1·Gd–1·Er compounds consist of a dimeric sub-building unit (SUB) of [Ln2(O2CR)4(NO3)2(MeOH)4], which is covalently-linked by cam2− to a 2D grid layer and the layer is extended into a 3D supramolecular network by hydrogen bonding. Compounds 2·Tb–2·Er feature a three-dimensional homochiral framework involving one-dimensional lanthanide–carboxylate chains that are aligned parallel to the [100] direction. Direct current (dc) magnetic susceptibility data were collected for these two series of compounds. The findings indicate that compound 1·Gd shows a Gd⋯Gd antiferromagnetic interaction through carboxylate bridges, with a coupling constant of J = −0.034 cm−1. Compounds 1·Tb–1·Er, and 2·Dy–2·Er are dominated by the depopulation of Stark levels, while 2·Tb exhibits ferromagnetic interaction between the Tb3+ ions. Interestingly, compounds 1·Dy and 2·Dy exhibit frequency-dependent out-of-phase signals in alternating current (ac) magnetic susceptibility measurements indicating their slow magnetic relaxation characteristics." @default.
• W2049717259 created "2016-06-24" @default.
• W2049717259 creator A5013710341 @default.
• W2049717259 creator A5016788068 @default.
• W2049717259 creator A5057574653 @default.
• W2049717259 date "2013-01-01" @default.
• W2049717259 modified "2023-09-25" @default.
• W2049717259 title "Two new series of rare-earth organic frameworks involving two structural architectures: syntheses, structures and magnetic properties" @default.
• W2049717259 cites W1913741299 @default.
• W2049717259 cites W1963725032 @default.
• W2049717259 cites W1964488262 @default.
• W2049717259 cites W1965529830 @default.
• W2049717259 cites W1968453494 @default.
• W2049717259 cites W1970393504 @default.
• W2049717259 cites W1970438480 @default.
• W2049717259 cites W1970766472 @default.
• W2049717259 cites W1972646318 @default.
• W2049717259 cites W1975227028 @default.
• W2049717259 cites W1985429836 @default.
• W2049717259 cites W1985656278 @default.
• W2049717259 cites W1986510139 @default.
• W2049717259 cites W1986752264 @default.
• W2049717259 cites W1988240683 @default.
• W2049717259 cites W1990918587 @default.
• W2049717259 cites W1994460970 @default.
• W2049717259 cites W1996365624 @default.
• W2049717259 cites W1999937609 @default.
• W2049717259 cites W2002421365 @default.
• W2049717259 cites W2003315612 @default.
• W2049717259 cites W2008151531 @default.
• W2049717259 cites W2008325702 @default.
• W2049717259 cites W2009249795 @default.
• W2049717259 cites W2009905912 @default.
• W2049717259 cites W2010738825 @default.
• W2049717259 cites W2011703666 @default.
• W2049717259 cites W2015909087 @default.
• W2049717259 cites W2018524996 @default.
• W2049717259 cites W2019941215 @default.
• W2049717259 cites W2020066900 @default.
• W2049717259 cites W2020203707 @default.
• W2049717259 cites W2020322901 @default.
• W2049717259 cites W2020779890 @default.
• W2049717259 cites W2022085591 @default.
• W2049717259 cites W2022167379 @default.
• W2049717259 cites W2025508459 @default.
• W2049717259 cites W2026745864 @default.
• W2049717259 cites W2027084591 @default.
• W2049717259 cites W2028811334 @default.
• W2049717259 cites W2029110588 @default.
• W2049717259 cites W2029327919 @default.
• W2049717259 cites W2036265717 @default.
• W2049717259 cites W2036613846 @default.
• W2049717259 cites W2042790154 @default.
• W2049717259 cites W2042854041 @default.
• W2049717259 cites W2042985176 @default.
• W2049717259 cites W2046323932 @default.
• W2049717259 cites W2046672736 @default.
• W2049717259 cites W2047043463 @default.
• W2049717259 cites W2056320405 @default.
• W2049717259 cites W2058217199 @default.
• W2049717259 cites W2059539984 @default.
• W2049717259 cites W2059897402 @default.
• W2049717259 cites W2061765766 @default.
• W2049717259 cites W2062219239 @default.
• W2049717259 cites W2064919865 @default.
• W2049717259 cites W2070068896 @default.
• W2049717259 cites W2070150426 @default.
• W2049717259 cites W2071473119 @default.
• W2049717259 cites W2076060446 @default.
• W2049717259 cites W2076939671 @default.
• W2049717259 cites W2079892902 @default.
• W2049717259 cites W2080235735 @default.
• W2049717259 cites W2080665513 @default.
• W2049717259 cites W2083885008 @default.
• W2049717259 cites W2085327832 @default.
• W2049717259 cites W2088210228 @default.
• W2049717259 cites W2088779916 @default.
• W2049717259 cites W2089740902 @default.
• W2049717259 cites W2091476518 @default.
• W2049717259 cites W2093080802 @default.
• W2049717259 cites W2094683017 @default.
• W2049717259 cites W2094732111 @default.
• W2049717259 cites W2096007357 @default.
• W2049717259 cites W2099497386 @default.
• W2049717259 cites W2101000826 @default.
• W2049717259 cites W2109477907 @default.
• W2049717259 cites W2112867858 @default.
• W2049717259 cites W2114559340 @default.
• W2049717259 cites W2118298691 @default.
• W2049717259 cites W2121904540 @default.
• W2049717259 cites W2123087792 @default.
• W2049717259 cites W2124594571 @default.
• W2049717259 cites W2125622961 @default.
• W2049717259 cites W2130850911 @default.
• W2049717259 cites W2136536632 @default.
• W2049717259 cites W2140007069 @default.
• W2049717259 cites W2141633836 @default.
• W2049717259 cites W2141821717 @default.

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