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• W2049724721 abstract "Enantioselective conjugate addition of Grignard reagents to enones, catalyzed by Cu-Taniaphos or Josiphos complex, affords chiral enolates. Ensuing one-pot Mannich reaction with TiCl4-generated imine leads to aminocarbonyl compounds with benzyloxycarbonyl-protected nitrogen. Both diastereomers of these compounds are isolated in moderate yields but high enantiomeric purities (up to er 97.5:2.5)." @default.
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• W2049724721 date "2011-12-08" @default.
• W2049724721 modified "2023-10-07" @default.
• W2049724721 title "Enantioselective One-Pot Conjugate Addition of Grignard Reagents to Cyclic Enones Followed by Amidomethylation" @default.
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• W2049724721 doi "https://doi.org/10.1021/jo202146f" @default.
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