Matches in SemOpenAlex for { <https://semopenalex.org/work/W2049773323> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W2049773323 endingPage "3717" @default.
- W2049773323 startingPage "3712" @default.
- W2049773323 abstract "The reduction of nitrogen bonded acetamidopentaamminecobalt(III) by chromium(II) has been studied. The acetamido complex is a reasonably strong acid attributed to the equilibrium[Formula: see text]which has a pK a of 2.16 ± 0.08 at 25.0° and μ = 0.01 M. The reduction process has the rate law[Formula: see text]For reduction of the conjugate base k = k NH K a and k NH = 5.23 × 10 −2 M −1 s −1 at 25.1°, with ΔH = 14.5 ± 2 kcal mol −1 and ΔS = 16 ± 6 e.u. respectively. The rate law is indicative of an inner-sphere process. The orientation of the ligand is thought to be important for the reduction of the acetamido and the related carboxylato complexes, and this is discussed." @default.
- W2049773323 created "2016-06-24" @default.
- W2049773323 creator A5040156260 @default.
- W2049773323 creator A5053284355 @default.
- W2049773323 date "1973-11-15" @default.
- W2049773323 modified "2023-09-23" @default.
- W2049773323 title "The Reduction of Acetamidopentaamminecobalt(III) by Chromium(II)" @default.
- W2049773323 doi "https://doi.org/10.1139/v73-554" @default.
- W2049773323 hasPublicationYear "1973" @default.
- W2049773323 type Work @default.
- W2049773323 sameAs 2049773323 @default.
- W2049773323 citedByCount "1" @default.
- W2049773323 crossrefType "journal-article" @default.
- W2049773323 hasAuthorship W2049773323A5040156260 @default.
- W2049773323 hasAuthorship W2049773323A5053284355 @default.
- W2049773323 hasConcept C111335779 @default.
- W2049773323 hasConcept C115900902 @default.
- W2049773323 hasConcept C116569031 @default.
- W2049773323 hasConcept C134306372 @default.
- W2049773323 hasConcept C145148216 @default.
- W2049773323 hasConcept C147789679 @default.
- W2049773323 hasConcept C155647269 @default.
- W2049773323 hasConcept C170493617 @default.
- W2049773323 hasConcept C178790620 @default.
- W2049773323 hasConcept C179104552 @default.
- W2049773323 hasConcept C185592680 @default.
- W2049773323 hasConcept C197336794 @default.
- W2049773323 hasConcept C2524010 @default.
- W2049773323 hasConcept C2776793192 @default.
- W2049773323 hasConcept C33923547 @default.
- W2049773323 hasConcept C511782168 @default.
- W2049773323 hasConcept C537208039 @default.
- W2049773323 hasConcept C55493867 @default.
- W2049773323 hasConcept C71240020 @default.
- W2049773323 hasConcept C8010536 @default.
- W2049773323 hasConceptScore W2049773323C111335779 @default.
- W2049773323 hasConceptScore W2049773323C115900902 @default.
- W2049773323 hasConceptScore W2049773323C116569031 @default.
- W2049773323 hasConceptScore W2049773323C134306372 @default.
- W2049773323 hasConceptScore W2049773323C145148216 @default.
- W2049773323 hasConceptScore W2049773323C147789679 @default.
- W2049773323 hasConceptScore W2049773323C155647269 @default.
- W2049773323 hasConceptScore W2049773323C170493617 @default.
- W2049773323 hasConceptScore W2049773323C178790620 @default.
- W2049773323 hasConceptScore W2049773323C179104552 @default.
- W2049773323 hasConceptScore W2049773323C185592680 @default.
- W2049773323 hasConceptScore W2049773323C197336794 @default.
- W2049773323 hasConceptScore W2049773323C2524010 @default.
- W2049773323 hasConceptScore W2049773323C2776793192 @default.
- W2049773323 hasConceptScore W2049773323C33923547 @default.
- W2049773323 hasConceptScore W2049773323C511782168 @default.
- W2049773323 hasConceptScore W2049773323C537208039 @default.
- W2049773323 hasConceptScore W2049773323C55493867 @default.
- W2049773323 hasConceptScore W2049773323C71240020 @default.
- W2049773323 hasConceptScore W2049773323C8010536 @default.
- W2049773323 hasIssue "22" @default.
- W2049773323 hasLocation W20497733231 @default.
- W2049773323 hasOpenAccess W2049773323 @default.
- W2049773323 hasPrimaryLocation W20497733231 @default.
- W2049773323 hasRelatedWork W1753750529 @default.
- W2049773323 hasRelatedWork W1969600162 @default.
- W2049773323 hasRelatedWork W1999685633 @default.
- W2049773323 hasRelatedWork W2023444917 @default.
- W2049773323 hasRelatedWork W2060532088 @default.
- W2049773323 hasRelatedWork W2326595344 @default.
- W2049773323 hasRelatedWork W2951454286 @default.
- W2049773323 hasRelatedWork W3005458064 @default.
- W2049773323 hasRelatedWork W3138501866 @default.
- W2049773323 hasRelatedWork W4231306477 @default.
- W2049773323 hasVolume "51" @default.
- W2049773323 isParatext "false" @default.
- W2049773323 isRetracted "false" @default.
- W2049773323 magId "2049773323" @default.
- W2049773323 workType "article" @default.