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- W2049801932 abstract "Abstract Ethanolic solutions of Rh III chloride exposed to γ-radiation under CO atmosphere are shown to be totally reduced into Rh I complexes (Rh 2 (CO) 4 Cl 2 and Rh(CO) 2 Cl - 2 ) within a few hours with a radiolytic reduction yield of about 6.0 elementary reductions/100 eV (6.2·10 -7 mol·J -1 ). The chloride ions freed in the medium inhibit further reduction through Rh(CO) 2 Cl - 2 formation. On addition of copper metal under the same conditions, Rh III is transformed into Rh 6 (CO) 16 with a conversion yield 50%. This cluster is formed via Rh 2 (CO) 4 Cl 2 although Rh(CO) 2 Cl - 2 is also present under these conditions. Rh 6 (CO) 16 cluster is also formed under radiolysis by direct reduction of Rh 2 (CO) 4 Cl 2 , but metallic rhodium and other reduced products are obtained at the same time." @default.
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- W2049801932 date "1988-01-01" @default.
- W2049801932 modified "2023-09-24" @default.
- W2049801932 title "Radiolytic synthesis of Rh2(CO)4Cl2 and Rh6(CO)16 from RhCl3 in ethanol under CO atmosphere" @default.
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- W2049801932 doi "https://doi.org/10.1016/1359-0197(88)90168-3" @default.
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