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- W2049813017 abstract "Abstract It is shown that the viscoelastic properties of silicates in the composition region of M2O:SiO2 ≈ 1 (where M is a monovalent cation or half of a divalent one) are identical and independent of composition if results are plotted with the glass transition as the reference temperature. This implies that either the structure of the material is independent of composition, which is unlikely in view of previous results of other workers, or that a rapid bond interchange reaction is present which determines the long-time viscoelastic behaviour. It is also shown that the glass transition temperature varies with the nature of the counterion in the same manner as in the phosphates in which no bond interchange occurs, which indicates that the glass transition mechanism in the silicates is a loosening of electrostatic interactions rather than bond interchange." @default.
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- W2049813017 date "1970-05-01" @default.
- W2049813017 modified "2023-10-16" @default.
- W2049813017 title "Viscoelasticity of silicate polymers and its structural implications" @default.
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- W2049813017 doi "https://doi.org/10.1016/0022-3093(70)90183-3" @default.
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