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- W2049815512 abstract "Abstract The reactions of Vaska’s complex [IrCl(CO)(PPh3)2] with 2-(coumaryl-6-azo)imidazole (CZ-H) and its derivatives (CZ-X) have synthesized [Ir(CZ)(CO)(PPh3)2] and [Ir(CZ-X)(CO)(PPh3)2]. All the complexes have been characterized by FT-IR, UV–Vis, 1H NMR and FAB-MS spectroscopy. The structural confirmation has been done in one case, by a single crystal X-ray diffraction study, which shows a distorted square pyramidal geometry around the central Ir atom. The complexes are emissive at room temperature. The cyclic voltammetry of the complexes shows a metal centered irreversible oxidation and ligand centered quasireversible reduction couples. To get an insight into the electronic structure, absorption spectra and electrochemical properties, detailed calculations on all three complexes have been performed at the DFT level." @default.
- W2049815512 created "2016-06-24" @default.
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- W2049815512 date "2011-05-01" @default.
- W2049815512 modified "2023-10-18" @default.
- W2049815512 title "Ir(I)–carbonyl complexes of coumarinazoimidazoles: Synthesis structure, electrochemistry, photophysical properties and DFT calculations" @default.
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- W2049815512 doi "https://doi.org/10.1016/j.poly.2011.03.021" @default.
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