Matches in SemOpenAlex for { <https://semopenalex.org/work/W2049834714> ?p ?o ?g. }
- W2049834714 endingPage "13374" @default.
- W2049834714 startingPage "13365" @default.
- W2049834714 abstract "Unraveling the kinetics and mechanisms of sparingly soluble calcium orthophosphate (Ca–P) dissolution in the presence of organic acids at microscopic levels is important for an improved understanding in determining the effectiveness of organic acids present in most rhizosphere environments. Herein, we use in situ atomic force microscopy (AFM) coupled with a fluid reaction cell to image dissolution on the (010) face of brushite, CaHPO4·2H2O, in citrate-bearing solutions over a broad concentration range. We directly measure the dependence of molecular step retreat rate on citrate concentration at various pH values and ionic strengths, relevant to soil solution conditions. We find that low concentrations of citrate (10–100 μM) induced a reduction in step retreat rates along both the [1̅00]Cc and [101̅]Cc directions. However, at higher concentrations (exceeding 0.1 mM), this inhibitory effect was reversed with step retreat speeds increasing rapidly. These results demonstrate that the concentration-dependent modulation of nanoscale Ca–P phase dissolution by citrate may be applied to analyze the controversial role of organic acids in enhancing Ca–P mineral dissolution in a more complex rhizosphere environment. These in situ observations may contribute to resolving the previously unrecognized interactions of root exudates (low molecular weight organic acids) and sparingly soluble Ca–P minerals." @default.
- W2049834714 created "2016-06-24" @default.
- W2049834714 creator A5000815865 @default.
- W2049834714 creator A5022239340 @default.
- W2049834714 creator A5031389433 @default.
- W2049834714 creator A5062451691 @default.
- W2049834714 creator A5081117163 @default.
- W2049834714 date "2013-11-19" @default.
- W2049834714 modified "2023-09-25" @default.
- W2049834714 title "Direct Imaging of Nanoscale Dissolution of Dicalcium Phosphate Dihydrate by an Organic Ligand: Concentration Matters" @default.
- W2049834714 cites W1935199567 @default.
- W2049834714 cites W1968225400 @default.
- W2049834714 cites W1968334466 @default.
- W2049834714 cites W1970032571 @default.
- W2049834714 cites W1973096644 @default.
- W2049834714 cites W1973511994 @default.
- W2049834714 cites W1977331002 @default.
- W2049834714 cites W1980496938 @default.
- W2049834714 cites W1982837210 @default.
- W2049834714 cites W1983318138 @default.
- W2049834714 cites W1984496125 @default.
- W2049834714 cites W1987285774 @default.
- W2049834714 cites W1989150745 @default.
- W2049834714 cites W1992191754 @default.
- W2049834714 cites W1993781553 @default.
- W2049834714 cites W1997868073 @default.
- W2049834714 cites W1998307303 @default.
- W2049834714 cites W2000698443 @default.
- W2049834714 cites W2006695600 @default.
- W2049834714 cites W2011557030 @default.
- W2049834714 cites W2013496911 @default.
- W2049834714 cites W2016721948 @default.
- W2049834714 cites W2018126576 @default.
- W2049834714 cites W2018636783 @default.
- W2049834714 cites W2020459452 @default.
- W2049834714 cites W2020953387 @default.
- W2049834714 cites W2021828663 @default.
- W2049834714 cites W2022455203 @default.
- W2049834714 cites W2025011021 @default.
- W2049834714 cites W2033684041 @default.
- W2049834714 cites W2036412160 @default.
- W2049834714 cites W2040013461 @default.
- W2049834714 cites W2045481899 @default.
- W2049834714 cites W2046587789 @default.
- W2049834714 cites W2052225207 @default.
- W2049834714 cites W2054264203 @default.
- W2049834714 cites W2055486715 @default.
- W2049834714 cites W2067608390 @default.
- W2049834714 cites W2070419897 @default.
- W2049834714 cites W2079519191 @default.
- W2049834714 cites W2079521213 @default.
- W2049834714 cites W2079798368 @default.
- W2049834714 cites W2081428192 @default.
- W2049834714 cites W2081944400 @default.
- W2049834714 cites W2082728435 @default.
- W2049834714 cites W2086542232 @default.
- W2049834714 cites W2090461399 @default.
- W2049834714 cites W2092912510 @default.
- W2049834714 cites W2093407552 @default.
- W2049834714 cites W2100194516 @default.
- W2049834714 cites W2128778774 @default.
- W2049834714 cites W2132698675 @default.
- W2049834714 cites W2133266834 @default.
- W2049834714 cites W2139493979 @default.
- W2049834714 cites W2139894928 @default.
- W2049834714 cites W2150295685 @default.
- W2049834714 cites W2154471797 @default.
- W2049834714 cites W2165268033 @default.
- W2049834714 cites W2168125769 @default.
- W2049834714 cites W2169947434 @default.
- W2049834714 cites W2171537317 @default.
- W2049834714 cites W2315698644 @default.
- W2049834714 cites W2317467915 @default.
- W2049834714 cites W375149308 @default.
- W2049834714 cites W4296766141 @default.
- W2049834714 cites W46837777 @default.
- W2049834714 doi "https://doi.org/10.1021/es402748t" @default.
- W2049834714 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24251349" @default.
- W2049834714 hasPublicationYear "2013" @default.
- W2049834714 type Work @default.
- W2049834714 sameAs 2049834714 @default.
- W2049834714 citedByCount "37" @default.
- W2049834714 countsByYear W20498347142014 @default.
- W2049834714 countsByYear W20498347142015 @default.
- W2049834714 countsByYear W20498347142016 @default.
- W2049834714 countsByYear W20498347142017 @default.
- W2049834714 countsByYear W20498347142018 @default.
- W2049834714 countsByYear W20498347142019 @default.
- W2049834714 countsByYear W20498347142020 @default.
- W2049834714 countsByYear W20498347142021 @default.
- W2049834714 countsByYear W20498347142022 @default.
- W2049834714 countsByYear W20498347142023 @default.
- W2049834714 crossrefType "journal-article" @default.
- W2049834714 hasAuthorship W2049834714A5000815865 @default.
- W2049834714 hasAuthorship W2049834714A5022239340 @default.
- W2049834714 hasAuthorship W2049834714A5031389433 @default.
- W2049834714 hasAuthorship W2049834714A5062451691 @default.
- W2049834714 hasAuthorship W2049834714A5081117163 @default.