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- W2049866564 abstract "The complexes AgMoO–4, Ag2MoO4 and Ag(MoO4)3–2 have been shown to exist in molten 1:1 (K, Na)NO3 and the corresponding stability constants, βmn, have been determined by potentiometry and solubility measurements. The complexes are weak and e.m.f. measurements give by far the best estimate of β11 for AgMoO–4. Changes in β11 in the interval 524 < T/K < 622 are analysed in terms of ΔH°1 and ΔS°1 for the association process. ΔH°1 and –TΔS°1 contribute to about the same extent to ΔG°1. This thermodynamic pattern is rather similar to that of AgCrO–4 formation in the same solvent, but the present results indicate the possibility of slightly stronger Ag—O bonding in the MoO2–4 system. A continuous range of solid solutions (Ag, Na)2MoO4 with the Ag1 fraction ranging from 1 to 0.4 has been observed at 553 K. An analysis of distribution equilibria between solids and melts shows that the (Ag, Na)2MoO4 solids can be treated as regular cationic substitutional solutions with an interaction parameter A= 9.6 ± 0.5 kJ mol–1." @default.
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- W2049866564 date "1981-01-01" @default.
- W2049866564 modified "2023-09-26" @default.
- W2049866564 title "Thermodynamics of solid solutions (Ag, Na)2MoO4 and silver molybdate complexation in molten (K, Na)NO3. Potentiometric and solubility study" @default.
- W2049866564 doi "https://doi.org/10.1039/f19817700101" @default.
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