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- W2049893556 abstract "A new mechanism for enhancing the visible light absorption of a homogeneous polyoxovanadate system is described. The photoactive pentanuclear {V(5)} isopolyoxovanadate cluster is formed in situ by a thermally-induced condensation reaction starting from a tetranuclear {V(4)} precursor. Upon irradiation with visible light, {V(5)} undergoes a light induced reduction reaction resulting in the formation of a 2-electron reduced {V(10)} cluster. Simultaneously, the oxidant methanol is selectively oxidized to formaldehyde. The {V(10)} cluster can subsequently be re-oxidized using H(2)O(2) or O(2)." @default.
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- W2049893556 date "2011-01-01" @default.
- W2049893556 modified "2023-09-24" @default.
- W2049893556 title "Tuning the light absorption of a molecular vanadium oxide system for enhanced photooxidation performance" @default.
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- W2049893556 doi "https://doi.org/10.1039/c0cc05536k" @default.
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