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- W2049901209 abstract "Aus den dimeren und tetrameren Trimethylstannylthio-Carbonylkomplexen 1 und 2 des Mangans und Rheniums lassen sich durch HCl-Spaltung die Komplexe [(CO)4MSH]2 3 und [(CO)3MSH]4 (M = Mn, Re) gewinnen. Von den Komplexen 3 lassen sich syn-and anti-Isomere nachweisen und ineinander überführen. CO unter Druck verwandelt die Komplexe 4 in 3 und den Mangankomplex 3a in das monomere (CO)5MnSH (5a), das sich jedoch sehr schnell wieder in 3a zurückverwandelt. Mercapto-Carbonyl Complexes of Manganese and Rhenium The dimeric and tetrameric trimethylstannylthio carbonyl complexes of manganese and rhenium 1 and 2 can be cleaved by HCl to form the complexes [CO)4MSH]2 3 and [CO)3MSH]4 4 (M = Mn, Re). Of the complexes 3, syn-and anti-isomers can be identified and interconverted. CO under pressure converts the complexes 4 into 3 and the manganese complexe 3a into monomeric (CO)5MnSH(5a), which, however, is quickly reconverted into 3a." @default.
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- W2049901209 date "1976-04-01" @default.
- W2049901209 modified "2023-10-14" @default.
- W2049901209 title "Mercapto‐Carbonyl‐Komplexe des Mangans und Rheniums" @default.
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- W2049901209 doi "https://doi.org/10.1002/cber.19761090441" @default.
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