FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2049928134> ?p ?o ?g. }

• W2049928134 endingPage "40" @default.
• W2049928134 startingPage "40" @default.
• W2049928134 abstract "Environmental Context.Since the early 1990s, methyl tert-butyl ether (MTBE), a possible human carcinogen, has been used as a gasoline oxygenate at concentrations of up to 15% by volume; however, a fraction of the MTBE produced has inevitably been released to the environment. And, spills at gasoline service stations have resulted in local groundwater contamination levels of MTBE over 100 mg L−1, because of its very high water solubility. Advanced oxidation is a common technique for mineralizing organic contaminants, but the reaction chemistry needs to be better understood to facilitate design of remediation systems. Abstract.A kinetic model for the degradation of methyl tert-butyl ether (MTBE) in batch reactors with Fenton’s oxidation (Fe2+/ H2O2) in aqueous solutions was developed. This kinetic model consists of equations accounting for (1) hydrogen peroxide chemistry in aqueous solution, (2) iron speciation, and (3) MTBE oxidation. The mechanisms of MTBE degradation, and the resultant pathways for the formation and degradation of the byproducts, were proposed on the basis of previous studies. A set of stiff nonlinear ordinary differential equations that describe the rate of formation of each species in this batch system was solved using Matlab (R13) software. The kinetic model was validated with published experimental data. The degradation of MTBE by Fenton’s oxidation is predicted well by the model, as are the formation and degradation of byproducts, especially methyl acetate (MA) and tert-butyl alcohol (TBA). Finally, a sensitivity analysis based on calculating the sum of the squares of the residuals (SSR) after making a perturbation of one rate constant at a time was applied to discern the effect of each reaction on MTBE disappearance." @default.
• W2049928134 created "2016-06-24" @default.
• W2049928134 creator A5055116273 @default.
• W2049928134 creator A5083171370 @default.
• W2049928134 creator A5087492370 @default.
• W2049928134 date "2006-01-01" @default.
• W2049928134 modified "2023-09-30" @default.
• W2049928134 title "Kinetic Model for the Degradation of MTBE by Fenton's Oxidation" @default.
• W2049928134 cites W1926950498 @default.
• W2049928134 cites W1964236123 @default.
• W2049928134 cites W1966817137 @default.
• W2049928134 cites W1972791191 @default.
• W2049928134 cites W1973658464 @default.
• W2049928134 cites W1974821897 @default.
• W2049928134 cites W1975043058 @default.
• W2049928134 cites W1978224564 @default.
• W2049928134 cites W1980857424 @default.
• W2049928134 cites W1982979079 @default.
• W2049928134 cites W1985521602 @default.
• W2049928134 cites W1986909143 @default.
• W2049928134 cites W1989501933 @default.
• W2049928134 cites W1996691467 @default.
• W2049928134 cites W2001546444 @default.
• W2049928134 cites W2001861274 @default.
• W2049928134 cites W2005456734 @default.
• W2049928134 cites W2010662953 @default.
• W2049928134 cites W2013187897 @default.
• W2049928134 cites W2018610252 @default.
• W2049928134 cites W2021697839 @default.
• W2049928134 cites W2022548675 @default.
• W2049928134 cites W2028003186 @default.
• W2049928134 cites W2031392153 @default.
• W2049928134 cites W2037108150 @default.
• W2049928134 cites W2041647635 @default.
• W2049928134 cites W2045371411 @default.
• W2049928134 cites W2047979779 @default.
• W2049928134 cites W2051802937 @default.
• W2049928134 cites W2055159418 @default.
• W2049928134 cites W2058068227 @default.
• W2049928134 cites W2059435078 @default.
• W2049928134 cites W2059544900 @default.
• W2049928134 cites W2060913275 @default.
• W2049928134 cites W2060931675 @default.
• W2049928134 cites W2063555010 @default.
• W2049928134 cites W2063690478 @default.
• W2049928134 cites W2070202149 @default.
• W2049928134 cites W2078100316 @default.
• W2049928134 cites W2083669451 @default.
• W2049928134 cites W2089869453 @default.
• W2049928134 cites W2112027230 @default.
• W2049928134 cites W2341714174 @default.
• W2049928134 cites W246191550 @default.
• W2049928134 cites W307000743 @default.
• W2049928134 cites W77941366 @default.
• W2049928134 doi "https://doi.org/10.1071/en05044" @default.
• W2049928134 hasPublicationYear "2006" @default.
• W2049928134 type Work @default.
• W2049928134 sameAs 2049928134 @default.
• W2049928134 citedByCount "10" @default.
• W2049928134 countsByYear W20499281342019 @default.
• W2049928134 countsByYear W20499281342021 @default.
• W2049928134 countsByYear W20499281342022 @default.
• W2049928134 crossrefType "journal-article" @default.
• W2049928134 hasAuthorship W2049928134A5055116273 @default.
• W2049928134 hasAuthorship W2049928134A5083171370 @default.
• W2049928134 hasAuthorship W2049928134A5087492370 @default.
• W2049928134 hasConcept C103697071 @default.
• W2049928134 hasConcept C107872376 @default.
• W2049928134 hasConcept C108285982 @default.
• W2049928134 hasConcept C112570922 @default.
• W2049928134 hasConcept C151730666 @default.
• W2049928134 hasConcept C161790260 @default.
• W2049928134 hasConcept C178790620 @default.
• W2049928134 hasConcept C184651966 @default.
• W2049928134 hasConcept C185592680 @default.
• W2049928134 hasConcept C18903297 @default.
• W2049928134 hasConcept C2778540947 @default.
• W2049928134 hasConcept C2779343474 @default.
• W2049928134 hasConcept C2779679103 @default.
• W2049928134 hasConcept C2780407432 @default.
• W2049928134 hasConcept C41008148 @default.
• W2049928134 hasConcept C522964758 @default.
• W2049928134 hasConcept C76155785 @default.
• W2049928134 hasConcept C86803240 @default.
• W2049928134 hasConceptScore W2049928134C103697071 @default.
• W2049928134 hasConceptScore W2049928134C107872376 @default.
• W2049928134 hasConceptScore W2049928134C108285982 @default.
• W2049928134 hasConceptScore W2049928134C112570922 @default.
• W2049928134 hasConceptScore W2049928134C151730666 @default.
• W2049928134 hasConceptScore W2049928134C161790260 @default.
• W2049928134 hasConceptScore W2049928134C178790620 @default.
• W2049928134 hasConceptScore W2049928134C184651966 @default.
• W2049928134 hasConceptScore W2049928134C185592680 @default.
• W2049928134 hasConceptScore W2049928134C18903297 @default.
• W2049928134 hasConceptScore W2049928134C2778540947 @default.
• W2049928134 hasConceptScore W2049928134C2779343474 @default.
• W2049928134 hasConceptScore W2049928134C2779679103 @default.
• W2049928134 hasConceptScore W2049928134C2780407432 @default.

• next