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- W2049930849 abstract "The complex formation of 3,5-dimethylpyrazole-1-carboxamidinium nitrate, HL·HNO3 with ammine complexes of cadmium(II) halides (Cl, Br, I) and zinc(II) chloride has been investigated under self-controlled reaction conditions. The complexes have been characterized by X-ray diffraction, FT-IR spectroscopy, thermal analysis and quantum chemical calculations. In the case of cadmium bromide and iodide salts, isostructural complexes with composition of [CdX2(HL)2] were formed. With CdCl2 a binuclear octahedral [Cd2(HL)4(μ-Cl)2](NO3)2 complex is obtained. Zinc(II) chloride with HL·HNO3 gives [Zn(HL)2Cl]NO3, the zinc center exhibiting severely distorted five-coordinate stereochemistry, intermediate between an ideal trigonal bipyramid and a square pyramid. The course of complex formation as well as the thermal properties of the compounds has been explained using the HSAB principle. The assignment of the FT-IR spectra was supported by DFT computations." @default.
- W2049930849 created "2016-06-24" @default.
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- W2049930849 date "2009-11-01" @default.
- W2049930849 modified "2023-09-26" @default.
- W2049930849 title "Transition metal complexes with pyrazole-based ligands. Part 28. Synthesis, structural, DFT and thermal studies of cadmium(II) halides and zinc(II) chloride complexes with 3,5-dimethylpyrazole-1-carboxamidine" @default.
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- W2049930849 doi "https://doi.org/10.1016/j.poly.2009.08.020" @default.
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