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- W2049968693 abstract "Erstmals erhielten wir rosa-violette Einkristalle von Cs2Na[TiF6] durch eine „Redoxreaktion mit der Wand”︁ gemäß Cs2Na[CuF6] + Ti Cs2Na[TiF6] + Cu. Nach Guinier-deWolff-Daten zerriebener Einkristalle ist a = 6,2879(9) und c = 15,309(3) Å mit c/a = 2,4347. Die Struktur wurde mittels Vierkreisdiffraktometerdaten (R.Gr. Nr. 164, P3m1-D3d) aufgeklärt; Parameter siehe Text. Der Aufbau entspricht dem von HT-K2Li[AlF6] (R.Gr. 156, P3m1-C3v); zeigt also die 6L-Abfolge von RbZnF3. Der Madelunganteil der Gitterenergie, MAPLE, sowie Effektive Koordinationszahlen, ECoN, werden über Mittlere Fiktive Ionenradien, MEFIR, berechnet und diskutiert. On Cs2Na[TiF6]. Another Example of the 6-Layer Structure By “redox-reaction with the wall” according to Cs2Na[CuF6] + Ti Cs2Na[TiF6] + Cu we obtained for the first time single crystals of Cs2Na[TiF6]. The violet irregular single crystals of Cs2Na[TiF6] crystallize in accordance with the single-crystal studies in space group P3m1–D3d No. 164 with a = 6.2879(9) und c = 15.309(3) Å. It is a variant of the HT-modification of K2LiAlF6 which crystallizes in P3m1-C3v (WINKLER [2]). The Madelung Part of Lattice Energy, MAPLE, and the Effective Coordination Number, ECoN, via the Fictive Ionic Radii, MEFIR, are calculated and discussed." @default.
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- W2049968693 date "1989-01-01" @default.
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- W2049968693 title "Neues �ber Cs2Na[TiF6]. Ein weiterer Vertreter der 6-Layer-Struktur" @default.
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- W2049968693 doi "https://doi.org/10.1002/zaac.19895790103" @default.
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