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• W2049969765 abstract "Abstract Ligand exchange between 2-(diethylaminomethyl)-4-methylphenol (N∩OH) and ReOCl3(PPh3)2 yields green crystals of the zwitterionic complex ReOCl3(O∩NH)(PPh3). The X-ray diffraction study reveals that the structure consists of monomeric units in which the distorted octahedral coordination around Re is provided by the oxo group, the three Cl atoms in a mer arrangement, the PPh3 ligand and the phenolate oxygen trans to the oxo group. The amino–phenol is monodentate via the phenolate oxygen, whereas the amine in the side-arm has been quaternized by migration of the phenol proton. The resulting ammonium group forms an intramolecular NH⋯Cl hydrogen bond with an adjacent Cl ligand, making the complex highly resistant to deprotonation. The 1H NMR spectra indicate that the NH proton is not labile in CDCl3. Electron delocalisation along the OReOC(phenolate) moiety via the sp-hybridised oxygen of the end-on coordinated phenolate would be consistent with the short ReO(phenolate) distance of 1.915(3) A observed." @default.
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• W2049969765 date "1999-11-01" @default.
• W2049969765 modified "2023-10-15" @default.
• W2049969765 title "Synthesis, molecular and crystal structure of the zwitterionic Re(V)–oxo complex ReOCl3(L)(PPh3) with L=2-(diethylaminomethyl)-4-methylphenol" @default.
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• W2049969765 doi "https://doi.org/10.1016/s0020-1693(99)00384-9" @default.
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