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- W2050043231 abstract "New diketopiperazines, named maremycins C1/C2 (1a/1b) and D1/D2 (2a/2b), as well as the novel spiro-indoles, maremycins E (3) and F (4), have been detected alongside the known maremycin B (6) in the culture broth of Streptomyces sp. (strain GT 051237) by chemical screening. The structures have been determined by detailed NMR spectroscopic investigations of the isolated metabolites. Maremycins C1/C2 (1a/1b) as well as D1/D2 (2a/2b) are diastereomers and were identified as mixtures. Structurally, maremycins C1/C2 (1a/1b) are the diastereomers of the sulfur oxidation products of maremycin B (6), while D1/D2 (2a/2b) are the demethylmercapto analogues of maremycins A (5) and B (6), respectively. Maremycins E and F possess a novel structural skeleton, where a spiro moiety is formed between the 6-position of the cyclopenta[f]quinoxaline moiety and the 3′-position of the indol-2-one moiety of the initial diketopiperazine product." @default.
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- W2050043231 date "2001-01-01" @default.
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- W2050043231 title "Maremycins C and D, New Diketopiperazines, and Maremycins E and F, Novel Polycyclicspiro-Indole Metabolites Isolated fromStreptomycessp." @default.
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- W2050043231 doi "https://doi.org/10.1002/1099-0690(200101)2001:2<261::aid-ejoc261>3.0.co;2-6" @default.
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