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- W2050101038 abstract "A computer model was developed to simulate LDPE free radical polymerization at high pressure in either one- or two-zone tubular reactors. The model comprises a set of non-linear differential equations based on theoretical polymerization kinetics applied to a known reactor heat transfer profile. The predicted conversion and temperature profiles agreed with actual plant data within 10%. Calculated molecular weight distribution parameters were similar to measured data. The model is also capable of handling short and long chain branching. The sensitivity of reactor output and product molecular properties to various process variables, i.e., initiator systems, initiator injection modes, reactor jacket and ethylene inlet temperatures, reactor pressure, and ethylene split ratio can be projected using this model. Key features of the development of this model and several typical examples will be discussed." @default.
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- W2050101038 date "1986-01-01" @default.
- W2050101038 modified "2023-10-15" @default.
- W2050101038 title "A mathematical model for the production of low density polyethylene in a tubular reactor" @default.
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- W2050101038 doi "https://doi.org/10.1016/0009-2509(86)87189-5" @default.
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