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- W2050111809 abstract "Abstract The spectroscopic and photophysical parameters of the second excited singlet states of several enethiones have been measured in inert perfluoroalkane solvents. Two rigid, related enethiones, 1,1-dimethyl-2-thioxo-1,2-dihydronaphthalene thiocoumarin, behave in accordance with the energy gap law and decay predominately via S2 S1 T1. 1,1,3-Trimethyl-2-thioxo-1,2-dihydronaphthalene, with a methyl group at an sp2 carbon α to the thiocarbonyl moiety, exhibits a much faster non-radiative decay rate. Thioisophorone and 4H-pyran-4-thione are structurally flexible and decay non-radiatively from S2 at rates much faster than the rigid bicyclic enethione, thioverbenone. The results are rationalized in terms of the theory of radiationless transitions." @default.
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- W2050111809 date "1989-06-01" @default.
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- W2050111809 title "Photophysics of the second excited singlet states of cyclic enethiones" @default.
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- W2050111809 doi "https://doi.org/10.1016/1010-6030(89)87072-8" @default.
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