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- W2050117085 abstract "Die Darstellung der Methylenimmoniumsalze 3 (Tab. 1) gelingt durch Hydrid-Abstraktion aus der Methylgruppe der tertiären Amine 1 mittels Di- und Tri-aryl-methyl-Kationen 2. Die Salze 3 werden durch IR- und NMR-spektroskopische Untersuchungen charakterisiert. Reaktionen der Methylenimmoniumsalze 3 mit Grignardverbindungen (zu 5), Wasser (zu 6), Acetophenon (zur Mannich-Base 7) und N.N-Dimethylanilin (zu 8 und 9) werden beschrieben. Methylenimmonium Salts by Hydride Abstraction from Tertiary Amines The preparation of the methyleneimmonium salts 3 (table 1) is performed by hydride abstraction from methyl groups of the tertiary amines 1 by di- and triarylmethyl cations 2. The salts 3 are characterized by IR- and NMR-spectroscopic studies. Reactions of the methylenimmonium salts 3 with Grignard compounds (giving 5), water (→6), acetophenone (giving the Mannich base 7) and N,N-dimethylaniline (resulting in 8 and 9) are described." @default.
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- W2050117085 date "1971-10-29" @default.
- W2050117085 modified "2023-10-12" @default.
- W2050117085 title "Methylenimmoniumsalze durch Hydrid-Abstraktion aus tertiären Aminen" @default.
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- W2050117085 doi "https://doi.org/10.1002/jlac.19717520112" @default.
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