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- W2050161722 abstract "The crystal and molecular structures of the organomercury(II) complexes [Hg(C6H5)(chtsc)], 1, and [Hg(C6H5C5H4N)(btsc)], 2, obtained from the reaction of phenylmercury(II) acetate with cyclohexanone thiosemicarbazone (Hchtsc) and that of [2-(pyridin-2′-yl)]phenyl]mercury(II) acetate with benzaldehyde thiosemicarbazone (Hbtsc), respectively, are described. Both 1 and 2 are monoclinic, space group C2/c. Complex 1 has a distorted T-shaped geometry {C-Hg-S, 161.91(10)°} and 2 can be considered to have a distorted seesaw geometry {C-Hg-S, 171.2(10)°}. In both complexes the ligands act as bidentate chelating anions bonding through azomethine N1 and thiolato S atoms." @default.
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- W2050161722 date "2005-10-01" @default.
- W2050161722 modified "2023-10-11" @default.
- W2050161722 title "Crystal structures of organomercury(II) derivatives of cyclohexanone and benzaldehyde thiosemicarbazones" @default.
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- W2050161722 doi "https://doi.org/10.1080/00958970500241415" @default.
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