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- W2050173485 abstract "[reaction: see text] A mild, efficient, one-pot protocol for the cyclization of nitro-aryl substrates using SnCl(2) has been described. The mechanistic course of the reaction suggests the involvement of a hydroxylamine intermediate leading to an intramolecular cyclization via N-N bond formation. The versatility of the methodology has been demonstrated by using two nitro-aryl substrates derived from dihydroisoquinolines and dihydro-beta-carbolines. The intramolecular cyclization led to the formation of indazoles in high yields and purities." @default.
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- W2050173485 date "2006-03-21" @default.
- W2050173485 modified "2023-10-08" @default.
- W2050173485 title "Unprecedented SnCl<sub>2</sub>-Mediated Cyclization of Nitro Arenes via N−N Bond Formation" @default.
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- W2050173485 doi "https://doi.org/10.1021/ol053033y" @default.
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